993 30 3680 4 19569 document 3680 Readme.txt text/plain 56cbf8c4fbaaa763d923579efc746a75 MD5 767 2020-03-30 09:07:49 https://researchdata.gla.ac.uk/993/5/Readme.txt 993 5 7 text/plain Text en public cc_by_4

Readme.txt

readme 3681 1 19575 document 3681 indexcodes.txt text/plain 7a1ebebf2d9d1ca3808fd05ebfa4ab39 MD5 435 2020-03-30 09:08:07 https://researchdata.gla.ac.uk/993/6/indexcodes.txt 993 6 6 text/plain other Generate index codes conversion from Audio to indexcodes en public

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http://eprints.org/relation/isVersionOf https://researchdata.gla.ac.uk/id/document/3680 http://eprints.org/relation/isVolatileVersionOf https://researchdata.gla.ac.uk/id/document/3680 http://eprints.org/relation/isIndexCodesVersionOf https://researchdata.gla.ac.uk/id/document/3680 3682 3 19580 document 3682 Archive.zip application/x-zip 6c3974c36c9c032c4d5998977997f1a1 MD5 28535341 2020-03-30 09:12:42 https://researchdata.gla.ac.uk/993/7/Archive.zip 993 7 5 application/x-zip Mixed en public cc_by_4

Archive.zip

data archive 5 disk0/00/00/09/93 2020-03-30 09:39:37 2024-04-15 14:21:45 2020-03-30 09:39:37 data_collection show Walton Finlay 36222 0000-0002-4739-1649 Bolling John 44941 Farrell Andrew 38097 MacEwen Jamie Syme Christopher 3245 0000-0002-0913-1141 Gonzalez Jimenez Mario 31706 0000-0002-8853-0588 Senn Hans 6005 0000-0001-8232-5957 Wilson Claire 32950 0000-0002-0090-5374 Cinque Gianfelice Wynne Klaas 15668 0000-0002-5305-5940 glaresearchdata:2020-03-26-993 pub 30100000 Funding also acknowledged from EPSRC (EP/J004812/1). Liquid-liquid transitions between two amorphous phases in a single-component liquid (polyamorphism) have defied explanation and courted controversy. All known examples of liquid–liquid transitions have been observed in the supercooled liquid suggesting an intimate connection with vitrification and locally favored structures inhibiting crystallization. However, there is precious little information about the local molecular packing in supercooled liquids meaning that the order parameter of the transition is still unknown. Here, we investigate the liquid–liquid transition in triphenyl phosphite and show that it is caused by the competition between liquid structures that mirror two crystal polymorphs. The liquid–liquid transition is found to be between a geometrically frustrated liquid to a dynamically frustrated glass. These results indicate a general link between polymorphism and polyamorphism and will lead to a much greater understanding of the physical basis of liquid–liquid transitions and allow the discovery of other examples. 2020-03-26 published University of Glasgow 10.5525/gla.researchdata.993 Image Text 166308 Liquid-liquid transitions in molecular liquids: from supramolecular structure to phase separation Klaas Wynne Engineering and Physical Sciences Research Council (EPSRC) EP/J004790/1 Chemistry 166776 The structure and dynamics of water confined in nanoscale pools: the dynamic crossover Klaas Wynne Engineering and Physical Sciences Research Council (EPSRC) EP/J009733/1 Chemistry 190480 University of Glasgow - Equipment Account Muffy Calder Engineering and Physical Sciences Research Council (EPSRC) EP/J014478/1 S&E - College Senior Management 172399 Mapping and controlling nucleation Klaas Wynne Engineering and Physical Sciences Research Council (EPSRC) EP/N007417/1 Chemistry 303917 Delocalised phonon-like modes in organic and bio-molecules Klaas Wynne Leverhulme Trust (LEVERHUL) RPG-2018-350 Chemistry 304469 CONTROL Klaas Wynne European Commission (EC) 832703 Chemistry TRUE EN 2030-03-30 R FALSE FALSE https://eprints.gla.ac.uk/id/eprint/213422