449 29 1633 2 8344 document 1633 Co(Me2bipy)3_+_I2_NMR_fid application/octet-stream d175e6dfc6ea8c2781e2766127b6b557 MD5 296960 2017-08-24 13:07:21 https://researchdata.gla.ac.uk/449/1/Co%28Me2bipy%293_%2B_I2_NMR_fid 449 1 1 application/octet-stream Other en public cc_by_4

Co(Me2bipy)3_+_I2_NMR_fid

data 1634 3 8346 document 1634 Co(Me2bipy)3_NMR_fid application/octet-stream 269da8f1f9b3997b5dd5b9d87fa96775 MD5 296960 2017-08-24 13:07:24 https://researchdata.gla.ac.uk/449/2/Co%28Me2bipy%293_NMR_fid 449 2 2 application/octet-stream Other en public cc_by_4

Co(Me2bipy)3_NMR_fid

data 1635 3 8348 document 1635 Co(neo)1_NMR_fid application/octet-stream f8cd72039a2908d6769dd22891841d51 MD5 296960 2017-08-24 13:07:28 https://researchdata.gla.ac.uk/449/3/Co%28neo%291_NMR_fid 449 3 3 application/octet-stream Other en public cc_by_4

Co(neo)1_NMR_fid

data 1636 3 8350 document 1636 Co(neo)2_NMR_fid application/octet-stream 8aed34f2b474c151723966000269e142 MD5 296960 2017-08-24 13:07:33 https://researchdata.gla.ac.uk/449/4/Co%28neo%292_NMR_fid 449 4 4 application/octet-stream Other en public cc_by_4

Co(neo)2_NMR_fid

data 1637 3 8352 document 1637 Co(neo)3_+I2_NMR_fid application/octet-stream 040279c13b7c07960c20e74dacb6405d MD5 296960 2017-08-24 13:07:44 https://researchdata.gla.ac.uk/449/5/Co%28neo%293_%2BI2_NMR_fid 449 5 5 application/octet-stream Other en public cc_by_4

Co(neo)3_+I2_NMR_fid

data 1638 3 8354 document 1638 Co(neo)3_NMR_fid application/octet-stream 1fa244fe881cfd2ee80f9b7d81216660 MD5 296960 2017-08-24 13:07:49 https://researchdata.gla.ac.uk/449/6/Co%28neo%293_NMR_fid 449 6 6 application/octet-stream Other en public cc_by_4

Co(neo)3_NMR_fid

data 1639 3 8356 document 1639 Co(neo2)BF4_NMR_fid application/octet-stream a6e9adb7101fd1e87a8df03a6280568c MD5 296960 2017-08-24 13:07:54 https://researchdata.gla.ac.uk/449/7/Co%28neo2%29BF4_NMR_fid 449 7 7 application/octet-stream Other en public cc_by_4

Co(neo2)BF4_NMR_fid

data 1640 3 8358 document 1640 Co(phen)3_+_I2_NMR_fid application/octet-stream 8cbb404f38c989a411f5d9a0a4039d96 MD5 296960 2017-08-24 13:07:59 https://researchdata.gla.ac.uk/449/8/Co%28phen%293_%2B_I2_NMR_fid 449 8 8 application/octet-stream Other en public cc_by_4

Co(phen)3_+_I2_NMR_fid

data 1641 3 8360 document 1641 Co(phen)3_NMR_fid application/octet-stream 1fa8de5abdcdc36b5ef98d3951843682 MD5 296960 2017-08-24 13:08:07 https://researchdata.gla.ac.uk/449/9/Co%28phen%293_NMR_fid 449 9 9 application/octet-stream Other en public cc_by_4

Co(phen)3_NMR_fid

data 1642 3 8362 document 1642 Co(phen)4_NMR_fid application/octet-stream 33786f6ede44d9f669a810b73973eb57 MD5 296960 2017-08-24 13:08:10 https://researchdata.gla.ac.uk/449/10/Co%28phen%294_NMR_fid 449 10 10 application/octet-stream Other en public cc_by_4

Co(phen)4_NMR_fid

data 1643 3 8364 document 1643 Electrochemistry.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet 09c0c68aa76129243cc066b9c2f52ded MD5 274199 2017-08-24 13:08:13 https://researchdata.gla.ac.uk/449/11/Electrochemistry.xlsx 449 11 11 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet Spreadsheet en public cc_by_4

Electrochemistry.xlsx

data 1644 3 8366 document 1644 Infrared.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet ea25fb848d498b8b5de26ddeadaece21 MD5 63291 2017-08-24 13:08:17 https://researchdata.gla.ac.uk/449/12/Infrared.xlsx 449 12 12 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet Spreadsheet en public cc_by_4

Infrared.xlsx

data 1646 3 8370 document 1646 Readme_Symes_Supramolecular.docx application/vnd.openxmlformats-officedocument.wordprocessingml.document 959cb8ab5f33d5b6a3fb38daf8baa2c3 MD5 43621 2017-08-24 13:08:30 https://researchdata.gla.ac.uk/449/14/Readme_Symes_Supramolecular.docx 449 14 14 application/vnd.openxmlformats-officedocument.wordprocessingml.document Text en public cc_by_4

Readme_Symes_Supramolecular.docx

readme 1647 1 8384 document 1647 indexcodes.txt text/plain d5e48f4af9105a7acc546a928c52ab6f MD5 2471 2017-08-25 12:01:25 https://researchdata.gla.ac.uk/449/15/indexcodes.txt 449 15 15 text/plain other Generate index codes conversion from Text to indexcodes en public

indexcodes.txt

http://eprints.org/relation/isVersionOf https://researchdata.gla.ac.uk/id/document/1646 http://eprints.org/relation/isVolatileVersionOf https://researchdata.gla.ac.uk/id/document/1646 http://eprints.org/relation/isIndexCodesVersionOf https://researchdata.gla.ac.uk/id/document/1646 1651 2 8408 document 1651 Uv-vis.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet 10d0688245e417a9f6aac9095915b35a MD5 325841 2017-08-31 11:18:12 https://researchdata.gla.ac.uk/449/16/Uv-vis.xlsx 449 16 16 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet Spreadsheet en public cc_by_4

Uv-vis.xlsx

data archive 6975 disk0/00/00/04/49 2017-08-24 13:18:12 2017-09-26 13:11:31 2017-08-24 13:21:29 data_collection show Symes Mark D. Wilson Claire glaresearchdata:2017-08-24-449 30100000 Cobalt-diimine complexes have been used as structural and redox-active elements in a number of supramolecular assemblies. Frequently, it is necessary to functionalise the diimine ligand in order to incorporate it into a larger ensemble, and this can have a dramatic effect on the types of Co-diimine complexes that can form and their redox activity. Herein, we compare the solution-phase and redox chemistry of Co(II) complexes with 1,10-phenanthroline, 5,5′-dimethyl-2,2′-bipyridine and 2,9-dimethyl-1,10-phenanthroline (neocuproine), and show that in solutions containing Co(II) nitrate and neocuproine, the dominant species that forms is the mono-diimine complex [Co(neocuproine)(NO3)(CH3CN)2]+. The mono-neocuproine Co(II) complex is resistant to oxidation, either electrochemically or with iodine. We rationalise this behaviour by considering the steric constraints placed upon the metal centre by the bulky methyl substituents on the neocuproine ligand. Furthermore, from solutions of [Co(neocuproine)(NO3)(CH3CN)2]+, we isolate (and determine the structure of) crystals of formula [Co(neocuproine)2(NO3)]+·[Co(neocuproine)(NO3)3]− for the first time. We believe that this work will help to guide the development of Co-diimine supramolecular assemblies by highlighting the extent to which substituents close to the N-donor atoms can affect which species form in solution, and their likely redox activity. 2017-08-24 published University of Glasgow 10.5525/gla.researchdata.449 Mixed University of Glasgow 71460 1 Driving energetically uphill processes using metal-ligand coordination complexes Mark Symes The Royal Society (ROYSOC) UF150104 CHEM - CHEMISTRY TRUE English 2027-08-24 R FALSE FALSE http://eprints.gla.ac.uk/id/eprint/146582