Synthesis and magnetic studies of two Cu(II)/Zn(II) heterometallic complexes using bis-tris propane as a multidentate ligand.

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Murrie_2015_CuZn_MagData.xlsx

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http://eprints.org/relation/isVersionOf https://researchdata.gla.ac.uk/id/document/1374 http://eprints.org/relation/isVolatileVersionOf https://researchdata.gla.ac.uk/id/document/1374 http://eprints.org/relation/isIndexCodesVersionOf https://researchdata.gla.ac.uk/id/document/1374 archive 6975 disk0/00/00/02/01 2015-07-30 11:59:35 2025-06-09 12:51:21 2017-06-14 10:03:24 data_collection show Ojea Maria J.H. Wilson Claire 32950 0000-0002-0090-5374 Coles Simon J. Department of Chemistry, University of Southampton, Southampton, UK Tuna Floriana School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, UK Murrie Mark 9215 0000-0001-7297-2878 glaresearchdata:2015-10-14-201 Synthesis and magnetic studies of two Cu(II)/Zn(II) heterometallic complexes using bis-tris propane as a multidentate ligand. pub 30100000 Two new heterometallic complexes [Cu2Zn2(H4L)2(CH3COO)2Cl2]·2.5CH3OH·0.5H2O (1) and [Cu8Zn8(OH)8(H4L)8](Cl)2(ClO4)6·16H2O (2) have been synthesised following two different preparative routes, by using the polydentate ligand Bis–tris propane (H6L = 2,2′-(propane-1,3-diyldiimino)bis[2-(hydroxymethyl)propane-1,3-diol]). Herein, we describe the synthesis, structure, and magnetic properties of 1, a tetramer which forms in the absence of base and 2, a hexadecanuclear complex with a remarkable double-concentric ring structure that forms in the presence of base. Antiferromagnetic coupling between Cu(II) ions is observed in both compounds despite the long distances between paramagnetic metal centres, due to the involvement of diamagnetic Zn(II) ions in the magnetic exchange pathway. 2015-10-14 published University of Glasgow 10.5525/gla.researchdata.201 Mixed University of Glasgow 55588 1 Atom-by-atom control for the targeted chemical synthesis of heterometallic molecular nanomagnets Mark Murrie Engineering & Physical Sciences Research Council (EPSRC) EP/I027203/1 CHEM - CHEMISTRY FALSE English https://dx.doi.org/10.1039/C5DT03344F article 2034-12-31 R Review date of last access and update retention schedule accordingly. 2023-01-11 System note: This item was downloaded last on: Sat Jan 7 01:07:48 2023 so we could update the retention date to: 2033-01-07. It has had 90 downloads since 2013. 2025-06-09 MSM Updated retention date. Previous retention date was 2025-07-30. FALSE FALSE Directed synthesis of {CuII2ZnII2} and {CuII8ZnII8} heterometallic complexes http://eprints.gla.ac.uk/id/eprint/111017