200 25 168 3 1492 document 168 readme.txt text/plain ac8e99fcfc903b8028b2b549c6598d99 MD5 361 2015-07-15 09:45:51 https://researchdata.gla.ac.uk/200/1/readme.txt 200 1 1 text/plain Text en public cc_by_sa_4

readme.txt

readme 169 3 1494 document 169 N2 adsorption isotherms 77 K.zip application/x-zip 3e882b2bb929069dfb2de04d830b437b MD5 37122 2015-07-15 09:45:57 https://researchdata.gla.ac.uk/200/2/N2%20adsorption%20isotherms%2077%20K.zip 200 2 2 application/x-zip Machine_Instrument_Log en public cc_by_sa_4

N2 adsorption isotherms 77 K.zip

data 170 3 1496 document 170 NMR spectra - Bruker format.zip application/x-zip 1688e2925b01e56c7a357d90a6281765 MD5 25359415 2015-07-15 09:46:06 https://researchdata.gla.ac.uk/200/3/NMR%20spectra%20-%20Bruker%20format.zip 200 3 3 application/x-zip Machine_Instrument_Log en public cc_by_sa_4

NMR spectra - Bruker format.zip

data 171 3 1498 document 171 PXRD.zip application/x-zip c589b1e567f568aa715846c5b98c2392 MD5 78861 2015-07-15 09:46:10 https://researchdata.gla.ac.uk/200/4/PXRD.zip 200 4 4 application/x-zip Other en public cc_by_sa_4

PXRD.zip

data 172 3 1500 document 172 Raman Spectra.zip application/x-zip 9400059fd1175a293e6df19c19cc4fda MD5 199217 2015-07-15 09:46:19 https://researchdata.gla.ac.uk/200/5/Raman%20Spectra.zip 200 5 5 application/x-zip Machine_Instrument_Log en public cc_by_sa_4

Raman Spectra.zip

data 173 3 1502 document 173 TGA.zip application/x-zip a4cee4143248a10be7ae9da036c46c73 MD5 832101 2015-07-15 09:46:25 https://researchdata.gla.ac.uk/200/6/TGA.zip 200 6 6 application/x-zip Other en public cc_by_sa_4

TGA.zip

data 174 1 1512 document 174 indexcodes.txt text/plain 1ee53495ef754638d28ad937628b7627 MD5 274 2015-07-15 10:05:39 https://researchdata.gla.ac.uk/200/7/indexcodes.txt 200 7 7 text/plain other Generate index codes conversion from Text to indexcodes en public

indexcodes.txt

http://eprints.org/relation/isVersionOf https://researchdata.gla.ac.uk/id/document/168 http://eprints.org/relation/isVolatileVersionOf https://researchdata.gla.ac.uk/id/document/168 http://eprints.org/relation/isIndexCodesVersionOf https://researchdata.gla.ac.uk/id/document/168 archive 6975 disk0/00/00/02/00 2015-07-21 08:17:18 2025-06-09 12:42:16 2015-07-21 08:17:18 data_collection show Marshall Ross J. Griffrin Sarah L. Wilson Claire 32950 0000-0002-0090-5374 Forgan Ross 17300 0000-0003-4767-6852 glaresearchdata:2015-07-15-200 pub 30100000 The properties of metal-organic frameworks (MOFs) can be tuned by post-synthetic modification (PSM) to introduce specific functionalities after their synthesis. Typically, PSM is carried out on pendant functional groups or through metal/ligand exchange, preserving the structure of the MOF. We report herein the bromination of integral alkyne units in a pair of Zr4+ and Hf4+ MOFs, which proceeds stereoselectively in a single-crystal to single-crystal manner. The chemical and mechanical changes in the MOFs are ex-tensively characterised, including the crystal structures of the post-synthetically brominated materials, which show a mechanical contraction of up to 3.7% in volume. The combination of stability and chemical reactivity in these MOFs leads to the possibility of tuning mechanical properties by chemical transformation, while also opening up new routes to internal pore functionalization. 2015-07-15 published University of Glasgow 10.5525/gla.researchdata.200 Mixed 61947 1 Biomimetic guest selective metal-organic frameworks: catalysis and self-assembly Ross Forgan Engineering & Physical Sciences Research Council (EPSRC) EP/L004461/1 CHEM - CHEMISTRY FALSE EP/L004461/1 en http://pubs.acs.org/doi/abs/10.1021/jacs.5b05434 article 2035-03-31 R Check date of last access and update retention schedule accordingly. 2025-06-09 MSM Previous retention date was 2025-07-15. 32950 FALSE FALSE http://eprints.gla.ac.uk/id/eprint/108014