1520 21 6046 2 32788 document 6046 Open_access_data.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet c68b4c1822b7ee909871b2d51d4c592d MD5 825870 2023-10-30 11:34:20 https://researchdata.gla.ac.uk/1520/2/Open_access_data.xlsx 1520 2 2 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet Spreadsheet en public cc_by_4

Open_access_data.xlsx

data 6047 2 32791 document 6047 1520_readme.docx application/vnd.openxmlformats-officedocument.wordprocessingml.document 6247311bdcc7fa576d1b561b8822deeb MD5 837780 2023-10-30 11:34:34 https://researchdata.gla.ac.uk/1520/3/1520_readme.docx 1520 3 3 application/vnd.openxmlformats-officedocument.wordprocessingml.document Text en public cc_by_4

1520_readme.docx

readme 6048 1 32800 document 6048 indexcodes.txt text/x-c 7b1de63013f118adc37d02385de8943f MD5 4651 2023-10-30 11:44:43 https://researchdata.gla.ac.uk/1520/4/indexcodes.txt 1520 4 4 text/x-c other Generate index codes conversion from Text to indexcodes en public

indexcodes.txt

http://eprints.org/relation/isVersionOf https://researchdata.gla.ac.uk/id/document/6047 http://eprints.org/relation/isVolatileVersionOf https://researchdata.gla.ac.uk/id/document/6047 http://eprints.org/relation/isIndexCodesVersionOf https://researchdata.gla.ac.uk/id/document/6047 archive 32963 disk0/00/00/15/20 2023-10-30 11:40:16 2023-10-31 14:04:36 2023-10-30 11:40:16 data_collection show Alhathlaul Nada 52383 Ertekin Zeliha 65176 0000-0001-6106-7987 Symes Mark D. 15851 0000-0001-8067-5240 glaresearchdata:2023-10-30-1520 pub 30100000 Additional funding provided by Scientific and Technological Research Council of Turkey (TUBITAK 2219) and Jouf University, Saudi Arabia. The use of carbon dioxide as a comparatively cheap, abundant and non-toxic C-1 synthon is a topic of considerable interest and importance. The electrochemical addition of carbon dioxide across carbon-carbon double bonds is one of the more promising of such procedures, offering the possibility to convert a range of alkene substrates to valuable carboxylated products. However, much remains unknown about both the mechanism of reaction and how to influence product specificity during electro-carboxylation of alkenes. Herein, we explore the electrochemical addition of carbon dioxide (1 atm) to a range of olefinic substrates using nickel working electrodes and magnesium anodes at room temperature, producing the mono-substituted carboxylate derivatives preferentially (with no formation of the Markovnikov isomers of these mono-substituted carboxylate derivatives when the starting materials are non-symmetrical). These findings are rationalized using both experimental and computational methods, suggesting that the choice of Ni as a working electrode is critical in determining the reaction outcomes that are observed. Moreover, we also present direct evidence that a pathway whereby the alkene substrates are first reduced at the electrode surface and then react with dissolved CO2 is operating. Together, these results offer the potential for selective access to a range of valuable mono-carboxylic acids via the reduction of the corresponding alkene precursors in the presence of carbon dioxide. 2023-10-30 published University of Glasgow 10.5525/gla.researchdata.1520 Spreadsheet Text University of Glasgow 312636 Driving energetically uphill processes using metal-ligand coordination complexes - Renewal Mark Symes The Royal Society (ROYSOC) URF\R\211007 Chemistry 316623 Decoupled Electrolysis for the Production of Zero-Carbon Hydrogen Mark Symes Engineering and Physical Sciences Research Council (EPSRC) EP/W033135/1 Chemistry FALSE English https://authors.elsevier.com/sd/article/S1572-6657(23)00752-X article 2033-10-26 R email FALSE FALSE https://eprints.gla.ac.uk/id/eprint/308775