Data for Manuscript =================== Data for manuscript "Modulated Self-Assembly of an Interpenetrated MIL-53 Sc Metal-Organic Framework with Excellent Volumetric H2 Storage and Working Capacity” Mater. Today Chem. 2022, 24, 100887. Authors: A. J. R. Thom, D. G. Madden, R. Bueno-Perez, A. A.N. Al Shakhs, C. T. Lennon, R. J. Marshall, C. T. Walshe, C. Wilson, C. A. Murray, S. P. Thompson, G. F. Turner, D. Bara, S. A. Moggach, D. Fairen-Jimenez and R. S. Forgan* Experimental data in Origin format, Bruker NMR format, crystallographc information files and as jpg files The work has been supported in part by EPSRC (EP/L004461/1, EP/N509668/1) and the European Research Council (ERC) under the European Union's Horizon 2020 Programme for Research and Innovation (grant agreement no. 677289, SCoTMOF, ERC-2015-STG). S.A.M. thanks the Australian Research Council (ARC) for a Future Fellowship (FT200100243). G.F.T. acknowledges the Australian Government for the provision of an RTP scholarship. D.F.-J. thanks the Royal Society for receipt of a URF, the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (NanoMOFdeli), ERC-2016-COG 726380, Innovate UK (104384) and EPSRC IAA (IAA/RG85685). We acknowledge Diamond Light Source for time on I11 under proposal CY22028. CCDC 2095589-2095595 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. Data available NMR spectra, Thermogravimetric analysis, powder X-ray diffraction, nitrogen adsorption, SEM images.