A High-Pressure Crystallographic and Magnetic Study of Na5[Mn(L-tart)2]·12H2O (L-tart = L-tartrate)

Craig, G. A. and Woodall, C. H. and McKellar, S. C. and Probert, M. R. and Kamenev, K. V. and Moggach, S. A. and Brechin, E. K. and Parsons, S. and Murrie, M. (2015) A High-Pressure Crystallographic and Magnetic Study of Na5[Mn(L-tart)2]·12H2O (L-tart = L-tartrate). [Data Collection]

Original publication URL: http://dx.doi.org/10.1039/C5DT03320A

Collection description

The crystal structure and magnetic properties of the compound Na5[Mn(L-tart)2]•12H2O (1, L-tart = L-tartrate) have been investigated over the pressure range 0.34 – 3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

College / School: College of Science and Engineering > School of Chemistry
Date Deposited: 19 Aug 2015 08:32
Enlighten Publications URL: http://eprints.gla.ac.uk/110866/
Retention date: 30 September 2025
Funder's Name: Engineering & Physical Sciences Research Council (EPSRC)
URI: http://researchdata.gla.ac.uk/id/eprint/209

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Craig, G. A. and Woodall, C. H. and McKellar, S. C. and Probert, M. R. and Kamenev, K. V. and Moggach, S. A. and Brechin, E. K. and Parsons, S. and Murrie, M. (2015); A High-Pressure Crystallographic and Magnetic Study of Na5[Mn(L-tart)2]·12H2O (L-tart = L-tartrate)

University of Glasgow

10.5525/gla.researchdata.209

Retrieved: 2017-09-22

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