A High-Pressure Crystallographic and Magnetic Study of Na5[Mn(L-tart)2]·12H2O (L-tart = L-tartrate)

Craig, G. A., Woodall, C. H., McKellar, S. C., Probert, M. R., Kamenev, K. V., Moggach, S. A., Brechin, E. K., Parsons, S. and Murrie, M. (2015) A High-Pressure Crystallographic and Magnetic Study of Na5[Mn(L-tart)2]·12H2O (L-tart = L-tartrate). [Data Collection]

Original publication URL: http://dx.doi.org/10.1039/C5DT03320A
Enlighten Publications URI: http://eprints.gla.ac.uk/id/eprint/110866

Collection description

The crystal structure and magnetic properties of the compound Na5[Mn(L-tart)2]•12H2O (1, L-tart = L-tartrate) have been investigated over the pressure range 0.34 – 3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

College / School: College of Science and Engineering > School of Chemistry
Date Deposited: 19 Aug 2015 08:32
Enlighten Publications URL: http://eprints.gla.ac.uk/110866/
Retention date: 30 September 2025
Funder's Name: Engineering & Physical Sciences Research Council (EPSRC)
URI: http://researchdata.gla.ac.uk/id/eprint/209

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[error in script] (2015); A High-Pressure Crystallographic and Magnetic Study of Na5[Mn(L-tart)2]·12H2O (L-tart = L-tartrate)

University of Glasgow

10.5525/gla.researchdata.209

Retrieved: 2018-07-19